An ideal gas is heated from temperature T1 to temperature T2 by keeping its volume constant. The gas is expanded back to its initial temperature according to the law PVn = constant. If the entropy changes in the two processes are equal, find the value of n in terms of the adiabatic index γ

Change in entropy during constant volume process is given as:
= m cv ln (T2 / T1)
Change in entropy during polytropic process i.e. (PVn = constant)

= m cv [(γ – n)/ (n – 1)] ln (T2 / T1)

For the same entropy, equating both the above equations, we will get:
[(γ – n)/ (n – 1)] = 1
(γ – n) = (n – 1)
2n = γ +1
n = γ +1 / 2

Hence, the value of n in terms of the adiabatic index γ is equal to γ +1 / 2

Category: Second Law of Thermodynamics

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