Positive adsorption:
In case of adsorption by solids from the solutions, mostly the solute is adsorbed on the surface of the solid adsorbent so that the concentration of solute on the surface of the adsorbent is greater than in the bulk. This is known as positive adsorption. Hence when the concentration of the adsorbate is more on the surface of the adsorbent than in the bulk, it is known as positive adsorption.
Negative adsorption:
In some cases, the solvent from the solution may be adsorbed by the adsorbent so that the concentration of the solution increases than the initial concentration. This is called negative adsorption. Hence if the concentration of the adsorbate is less on the surface of the adsorbent than in the bulk, it is known as negative adsorption.