Ionic Equilibria

A saturated solution of H2S in water has concentration of approximately 0.10 M. What is the pH of this solution and equilibrium concentrations of H2S, HS– and S2-? Hydrogen sulphide is a diprotic acid and its dissociation constants are Ka1 = 9.1 x 10-8, Ka2 = 1.3 x 10-13 mol L-1 respectively.

The second dissociation constant is very small than the first dissociation constant and therefore, the concentration of H3O+ is obtained only from the first dissociation constant: H2S + H2O <…